4.3 Article Proceedings Paper

Synthesis of perfluoroalkyl thioethers from aromatic thiocyanates by iron-catalysed decarboxylative perfluoroalkylation

Journal

JOURNAL OF FLUORINE CHEMISTRY
Volume 198, Issue -, Pages 89-93

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2016.12.006

Keywords

Iron; Perfluoroalkylation; Perfluoroalkylthiolation; Decarboxylative couplings

Funding

  1. Deutsche Forschungsgemeinschaft [EXC 1069]

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Easily available aryl and heteroaryl thiocyanates were converted into the corresponding perfluoroalkyl thioethers via decarboxylation of potassium perfluoroalkylcarboxylates, catalysed by the inexpensive and environmentally benign iron(III) chloride. (C) 2016 Elsevier B.V. All rights reserved.

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