Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 196, Issue -, Pages 24-31Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2016.07.008
Keywords
Copper; Trifluoroethoxylation; Oxidative coupling; Aryl boronic acids; Aryl trifluoroethyl ethers
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Funding
- National Natural Science Foundation of China [21421002, 21332010, 21272036]
- National Basic Research Program of China [2012CB21600]
- Fundamental Research Funds for the Central Universities
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A mild and efficient copper-catalyzed oxidative trifluoroethoxylation of aryl and heteroaryl boronic acids with CF3CH2OH has been developed. This protocol tolerates a range of functional groups, allowing access to a variety of aryl and heteroaryl trifluoroethyl ethers. (C) 2016 Elsevier B.V. All rights reserved.
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