Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 203, Issue -, Pages 130-135Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2017.07.017
Keywords
Fluorodecarboxylation; Decarboxylative fluorination; Aryl trifluoromethyl ethers; Aryl trifluoromethyl thioethers; Aryloxydifluoroacetic acid; Arylmecaprodifluoroacetic acid
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Fluorodecarboxylation of aryloxydifluoroacetic acid (ArOCF2CO2H) and arylmercaptodifluoroacetic acid (ArSCF2CO2H) towards ArXCF3 (X = O, S) using silver (I) salts in the presence of Selectfluor in a biphasic system with trifluoroacetic acid additive is discussed.
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