Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 202, Issue -, Pages 76-81Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2017.08.013
Keywords
Phenoxyacetic herbicides; Fluorine analogs; Herbicidal activity; Fungistatic activity
Categories
Funding
- Polish Ministry of Science and Higher Education [4180/E-142/S/2016]
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Aryloxy fluoroacetic acids 3a-3h fluorine analogs of phenoxyacetic herbicides 2,4-D, MCPA, 2,4,5-T, and 4-CPA were efficiently synthesized in 29-88% yield, using appropriate phenols and either bromodifluoro- or bromofluoroacetic acid in the presence of sodium hydride as a base and in either dioxane or THE as solvents. Fluorine derivatives of 2,4-D (3a, 3b) show herbicidal activity against three weed species. Parent herbicides 2,4-D, MCPA, 2,4,5-T, 4-CPA, monofluorine derivatives of MCPA (3d) and 2,4,5-T (3f) show fungistatic activity against phytopatogenic fungi species Phytophtora cactorum.
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