4.4 Article

Dual-Functional Fluorescein-Based Chemosensor for Chromogenic Detection of Fe3+ and Fluorgenic Detection of HOCl

Journal

JOURNAL OF FLUORESCENCE
Volume 27, Issue 6, Pages 2111-2117

Publisher

SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s10895-017-2150-y

Keywords

Hypochlorite; Iron ion; Fluorescein; Dual functional; Fluorescence

Funding

  1. National Natural Science Foundation of China [21202130, 51603164]
  2. Fundamental Research Funds for the Central Universities [3102014JCQ15005]
  3. Natural Science Foundation Research Project of Shaanxi Province [2015JM2067]
  4. president Foundation of Xi'an Technological University [XAGDXJJ16010]

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A novel fluorescein-based dual probe was designed and synthesized. The probe exhibited highly sensitive and selective colormetric response to Fe3+ and turn-on fluorescence response towards OCl- with very low detection limits of 100 and 50 nM, respectively. It was successfully applied for quantitative detection of Fe3+ and OCl- in real water samples. Moreover, probe 1 was expected to be a potentially powerful tool for studying and providing further insights into OCl- and Fe3+ chemistry in the near future.

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