3.8 Proceedings Paper

High sensitivity fluorescence up-conversion spectroscopy of 3MLCT emission of metal-organic complexes

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E D P SCIENCES
DOI: 10.1051/epjconf/201920509009

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Funding

  1. ANR-DFG grant Femto-ASR [ANR-14-CE35-0015-01]
  2. ANR project PhotIron [ANR-16-CE07-0013-02]
  3. Labex NIE [ANR-11-LABX-0058_NIE]
  4. Region d'Alsace
  5. Agence Nationale de la Recherche (ANR) [ANR-14-CE35-0015, ANR-16-CE07-0013] Funding Source: Agence Nationale de la Recherche (ANR)

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We demonstrate the implementation of a broadband fluorescence up-conversion set-up with high signal-to-noise ratio and dynamic range allowing for the detection of weak luminescence from triplet states in Fe(II) NHC complexes. Based on the experimentally determined radiative rates and the emission spectra, these states have dominant MLCT character.

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