Journal
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 799, Issue -, Pages 122-125Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2017.05.054
Keywords
Iridium solvent complex; Electrochemiluminescence; Histidine; ECL probe
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Funding
- National Natural Science Foundation of China (NSFC) [21505097]
- Natural Science Foundation of Jiangsu Province [BK20150283]
- University Scientific Research Project of Jiangsu Province [15KJB150027]
- Collegiate Natural Science Fund of Jiangsu Province [16KJA430008]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Excellent Innovation Team in Science and Technology of University in Jiangsu Province
- Jiangsu Collaborative Innovation Center of Technology and Material for Water Treatment
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An iridium(III) solvent complex with non ECL emission has been synthesized and characterized by NMR, and cyclic voltammetry in this work. Under the potential stepping method in ProCell buffer solution, the electro-chemiluminescene (ECL) signals increase intensely along with the addition of histidine to this iridium(III) solvent complex buffer solution and it has much more selectivity to histidine over other amino acids, such as methionine, glycine, lysine, phenylalanine, valine, tryptophan and leucine. It's the first study to investigate an ECL probe to histidine detection based on this iridium(III) solvent complex, which may give much more inspiration for further exploring histidine or other biomolecules detection methods for electrochemical researchers.
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