Journal
SYNLETT
Volume 31, Issue 1, Pages 21-34Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-0039-1691496
Keywords
organosilicon; silanes; homogeneous catalysis; Lewis acid; silicon
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Funding
- National Natural Science Foundation of China [21703051, 21773051, 21801056]
- Natural Science Foundation of Zhejiang Province [LZ18B020001, LY17B030005, LY17E030003, LQ19B040001]
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The organosilicon-mediated organic synthesis (SiMOS) has attracted much attention over the recent decades. However, the use of organosilicon reagents with novel catalytic strategies remains to be explored. This Account summarizes our group's progress mainly based on the application of a wide variety of organosilicon reagents, including allylic silanes, trifluoromethyl silane, acylsilanes, chlorosilanes, hydrosilanes, trimethylsilyldiazomethane, trimethylsiloxyfuran, silanols, alpha-trimethylsilylmethylacetate, and trimethylsilylcyanide, in catalysis and organic reactions. These transformations were proved to be alternative procedures for the construction of structurally diverse compounds.
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