4.7 Article

A novel mesoporous hydrogen-bonded organic framework with high porosity and stability

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 1, Pages 66-69

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07802a

Keywords

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Funding

  1. National Natural Science Foundation of China [21971038, 21975044, 21805039, 21673039, 573042]
  2. Fujian Science and Technology Department [2019H6012, 2018J07001]
  3. China Postdoctoral Science Foundation [2018M642556]
  4. Welch Foundation [AX-1730]
  5. Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]

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A highly stable hydrogen-bonded organic framework, HOF-14, has been successfully constructed and structurally characterized. It possesses a permanent three dimensional (3D) porous structure. The activated HOF-14 has a high BET surface area of 2573 m(2) g(-1) and a record large pore volume of 1.36 cm(3) g(-1) among HOF materials. In addition, HOF-14 also exhibits high chemical and thermal stability and is capable of highly selective separation of light hydrocarbons under ambient conditions.

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