4.7 Article

Highly sensitive mechano-controlled luminescence in polymer films modified by dynamic CuI-based cross-linkers

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 1, Pages 50-53

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08354e

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Funding

  1. JSPS KAKENHI [JP18K05247]

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Dynamic Cu-I-based mechanophores used as cross-linkers in polybutylacrylates enable highly sensitive detection of mechanical stress even at small strain (<50%) and stress (<0.1 MPa) values via reversible changes in luminescence intensity. Such sensitivity is superior to previously reported systems based on classical organic mechanophores and it allows for direct visualization of mechanical stress by imaging methods.

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