Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 7, Issue 1, Pages 134-139Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9qi01229j
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Funding
- Ulm University
- Helmholtz-Gemeinschaft (HGF)
- Deutsche Forschungsgemeinschaft (DFG) [STR 1164/12, STR1164/14]
- Deutsche Forschungsgemeinschaft (Germany's Excellence Strategy, EXC-2154/1)
- Fonds der Chemischen Industrie (FCI)
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Molecular vanadium oxides are promising active materials for cathodes in lithium and post-lithium batteries due to their high redox activity, low molecular weight and facile tuneability. However, a major challenge for this application is the transformation of the molecular clusters into solid-state oxides under typical electrode fabrication conditions. Here, we report a molecular crystal engineering approach for the stabilization of molecular vanadium oxides in the crystal lattice, enabling initial studies on reversible electron storage in a lithium ion battery test cell.
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