An MOF-derived C@NiO@Ni electrocatalyst for N2 conversion to NH3 in alkaline electrolytes

Today, industrial ammonia synthesis mainly depends on the Haber-Bosch process, which causes a lot of energy consumption and huge CO2 emissions. The electrochemical N-2 reduction reaction (NRR) is considered a more sustainable and environmentally benign alternative to produce ammonia, but it requires an efficient catalyst to overcome the difficulty of N-2 activation. In this work, we reported that MOF-derived C@NiO@Ni microtubes behaved as a high-efficiency electrocatalyst in 0.1 M KOH electrolyte. This electrocatalyst achieved a high NH3 yield of 43.15 mg h(-1) mg(cat)(-1) and faradaic efficiency of 10.9% at -0.7 V vs. a reversible hydrogen electrode. The experimental results indicated that the excellent NRR performance originated from the oxygen vacancies in NiO. Moreover, the abundant NiO/Ni interfaces were conducive to proton adsorption and further enhanced the NRR performance.