4.7 Article

Colloidal syntheses of zero-dimensional Cs4SnX6 (X = Br, I) nanocrystals with high emission efficiencies

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 3, Pages 387-390

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08216f

Keywords

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Funding

  1. National Natural Science Foundation of China (NSFC) [51772142]
  2. Chinese Government [2017YFE0132300]
  3. Australian Government [2017YFE0132300]
  4. Guangdong Science and Technology Department [2016ZT06C279]
  5. Shenzhen Science and Technology Innovation Committee [JCYJ20170412152528921, KQTD2016053019134356, KQTD2016022619565991]
  6. Development and Reform Commission of Shenzhen Municipality (Shenzhen Engineering Research Center for Frontier Materials Synthesis at High Pressures)
  7. SUSTech Presidential Fund

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Phase-pure all-inorganic zero-dimensional (0D) tin halide Cs4SnX6 (X = Br, I) nanocrystals (NCs) are successfully prepared for the first time. The as-prepared Cs4SnBr6 NCs exhibit a strongly Stokes-shifted broadband emission with a high photoluminescence quantum yield (PLQY) of 21% at room temperature.

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