Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 18, Issue 2, Pages 263-271Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02294e
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Funding
- National Natural Science Foundation of China
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Polycyclic indole scaffolds are ubiquitous in pharmaceuticals and natural products and in materials science. Here, we present a visible-light-initiated intramolecular aryl migration/desulfonylation/cyclization cascade reaction for the synthesis of tetracyclic indolo[2,1-a]isoquinolin-6(5H)-ones. This protocol not only exhibited a wide substrate scope but also provided a mild route to access a variety of tetracyclic N-fused indoles.
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