Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 4, Pages 599-602Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08888a
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- Boehringer Ingelheim Stiftung via an Exploration Grant
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Herein, we report on a photochemical three-component reaction of aryldiazoacetates with NFSI and cyclic ethers. This method allows the introduction of both fluorine and a short ether sidechain using 1,4-dioxane as solvent in high yields via an ylide pathway as demonstrated by DFT calculations (26 examples, up to 99% yield).
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