4.7 Article

A novel low-bandgap pyridazine thiadiazole-based conjugated polymer with deep molecular orbital levels

Journal

POLYMER CHEMISTRY
Volume 11, Issue 2, Pages 581-585

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9py01137d

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Funding

  1. Russian Science Foundation [15-13-10022]
  2. Russian Science Foundation [15-13-10022] Funding Source: Russian Science Foundation

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A pyridazine thiadiazole acceptor (PzT) has been utilised in the synthesis of a novel low band-gap D-A copolymer PTTPz. It is a much stronger acceptor in comparison to BT and PyT moieties widely incorporated in the literature. Experimental results reveal that per electronegative N atom that is substituted into the acceptor, an effective HOMO and LUMO stabilization energy of similar to 0.2-0.1 eV can be achieved.

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