Journal
POLYMER CHEMISTRY
Volume 11, Issue 2, Pages 270-274Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9py01075k
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Funding
- China Scholarship Council (CSC) [201706240130]
- National Science Foundation Graduate Research Fellowships
- Yale University Lab Setup Funds
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An atom transfer radical polymerization-based sequential graft-from approach was developed to synthesize molecular brush-on-brush (MBoB)-based hierarchically branched polymers with readily tunable backbone grafting density, lengths of backbone and primary/secondary side chains, and monomer type. The hierarchically branched structure was visualized, and the stability of the giant MBoB macromolecules was studied by atomic force microscopy. The robust approach enabled the versatile combination of chemical functionality and MBoB structure.
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