Journal
REACTION CHEMISTRY & ENGINEERING
Volume 5, Issue 1, Pages 58-65Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9re00366e
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Funding
- Special Fund for Basic Scientific Research of Central Colleges, South-Central University for Nationalities [CZZ 19005]
- National Natural Science Foundation of China [2182175]
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There has been a great deal of attention to the development of heterogeneous non-noble metal catalysts for the selective and mild hydrogenation of nitro compounds into primary amines. Herein, a biomass-derived carbon material supported Ni catalyst (Ni/C) was facilely prepared by a one-pot pyrolysis process, and the as-prepared Ni/C catalyst demonstrated a high catalytic activity for the hydrogenation of nitro compounds into primary amines at room temperature. The Ni/C catalyst not only demonstrated a high catalytic activity but also showed a good tolerance to other functional groups. Structurally diverse primary amines were achieved in yields from 92% to 99% within a few hours at room temperature under 5 bar H-2. Furthermore, the Ni/C catalyst showed good reusability without the loss of its activity.
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