Journal
CHEMICAL SCIENCE
Volume 11, Issue 3, Pages 833-838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9sc04632a
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Funding
- Tianjin University
- Tianjin Government
- National Natural Science Foundation of China [51903188]
- Natural Science Foundation of Tianjin City [19JCQNJC04500]
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Molecular dimers have been frequently found to play an important role in room temperature phosphorescence (RTP), but its inherent working mechanism has remained unclear. Herein a series of unique characteristics, including singlet excimer emission and thermally activated delayed fluorescence, were successfully integrated into a new RTP luminogen of CS-2COOCH(3) to clearly reveal the excited-state process of RTP and the special role of molecular dimers in persistent RTP emission.
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