Journal
JOURNAL OF MATERIALS CHEMISTRY A
Volume 8, Issue 3, Pages 1335-1346Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ta11048h
Keywords
-
Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan through the Japan Society for the Promotion of Science (JSPS) [16H06293]
Ask authors/readers for more resources
Photocatalytic water splitting is the most ideal system to harvest solar energy for the production of useful chemicals. There have been many attempts to increase the photocatalytic activity of the TiO2 photocatalyst, such as loading co-catalysts and dopants, and the introduction of oxygen vacancies. Strain effects have also attracted much interest to increase the charge mobility in bulk oxide. Here, we report on the effectiveness of tensile strain in stabilizing the anatase phase of TiO2 at high temperature and increasing the photocatalytic activity by an increase in the charge separation with a unique mixed phase structure. The rate of H-2 formation over TiO2 was decreased upon spark plasma sintering (SPS) treatment because of a decrease in the surface area; however, SPS treatment with Au dispersion significantly increased the H-2 formation rate to higher than that over commercially available P-25 TiO2 (no SPS treatment) loaded with Au. The O-2 formation rate was also increased by strain effects in TiO2. Furthermore, strain effects were effective for visible light sensitivity on TiO2.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available