Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 22, Issue 3, Pages 966-970Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cp06017k
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A critical analysis of the role of Hammett basicity (H-) and aqueous basicity (pK(a)) in CO2 uptake in deep-eutectic solvents (DESs) suggests that neither H- nor pK(a) correlates with the CO2 w/w% capacity in the studied DESs. Instead, strong synergistic interactions between donor and acceptor moieties satisfactorily relate to the w/w% of CO2 in DESs.
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