4.7 Article

Metal-free C-C, C-O, C-S and C-N bond formation enabled by SBA-15 supported TFMSA

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 8, Pages 1243-1246

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc08389h

Keywords

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Funding

  1. National Natural Science Foundation of China [21901124]
  2. Natural Science Foundation of the Jiangsu Higher Education Institutions of China [19KJB150032]
  3. China Postdoctoral Science Foundation [2019M651809]

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The construction of intermolecular C-C, C-O, C-S and C-N bonds between diazo compounds and acyclic and cyclic 1,3-dicarbonyl compounds, thiophenol and alkynes was developed by using TFMSA@SBA-15, thus providing a metal-free and eco-friendly platform for forging those chemical bonds.

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