4.7 Article

Oxygen reduction using a metal-free naphthalene diimide-based covalent organic framework electrocatalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 8, Pages 1267-1270

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc06479f

Keywords

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Funding

  1. Spanish Government [MAT2016-77608-C3-1-P, MAT2016-77608-C3-2-P, CTQ2017-84309-C2-1-R, MAT2017-85089-C2-1-R, FJCI-2017-33536, RYC-2015-17730]
  2. UCM [INV.GR.00.1819.10759]
  3. Madrid Regional Government (TRANSNANOAVANSENS-CM) [S2018/NMT-4349]

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A novel naphthalene diimide-based covalent organic framework (NDI-COF) has been synthesized and successfully exfoliated into COF nanosheets (CONs). Electrochemical measurements reveal that the naphthalene diimide units incorporated into NDI-CONs act as efficient electrocatalyst for oxygen reduction in alkaline media, showing its potential for the development of metal-free fuel cells.

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