Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 18, Issue 4, Pages 666-670Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02489a
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Funding
- National Natural Science Foundation of China [81703330]
- Natural Science Foundation of Jiangsu Province [BK20170347]
- Priority Academic Program Development of the Jiangsu Higher Education Institutes (PAPD)
- Jiangsu Key Laboratory of Neuropsychiatric Diseases [BM2013003]
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A metal-free K2S2O8-HFIP synergistically promoted double Friedel-Crafts alkylation between a glycine derivative and N-substituted aniline was developed to efficiently synthesize diarylmethane derivatives with high para-selectivity. The reaction proceeded smoothly in the absence of any metal and ligand, and exhibited a good tolerance of functional groups.
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