Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 18, Issue 4, Pages 650-654Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02565k
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Funding
- National Natural Science Foundation of China [21672028, 21602019]
- Jiangsu Key Laboratory of Advanced Catalytic Materials Technology [BM2012110]
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A radical-initiated cascade addition and cyclization of N-allylbenzamides with simple ethers to construct ether-substituted dihydroisoquinolinones was performed in the presence of CuI. The cleavage of the sp(3) C-H bond in ether and the sp(2) C-H bond in phenyl was involved in this reaction. Moreover, the arylalkylation of N-allylanilines was also realized under similar reaction conditions, providing ether-functionalized indolines in good to moderate yields.
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