4.7 Article

Fused bis-azacalixphyrin that reaches NIR-II absorptions

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 6, Pages 896-899

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09021e

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Funding

  1. Centre National de la Recherche Scientifique
  2. Ministere de la Recherche et des Nouvelles Technologies
  3. Agence Nationale de la Recherche

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The fusion of two azacalixphyrin cycles absorbing in the NIR-I domain moves the absorption properties beyond 1000 nm, towards the second biological transparency window (NIR-II). This new type of NIR-II dye was synthesised through the intermediate preparation of a rare example of bis-tetra-azacalix[4]arene where the two macrocycles share a common aromatic unit.

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