4.7 Article

Single-ion copper doping greatly enhances catalytic activity of manganese oxides via electronic interactions

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 6, Pages 904-907

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc07669g

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Funding

  1. NSFC [21777030, 21976037]
  2. National Engineering Lab for Mobile Source Emission Control Technology [NELMS2018B02]

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Single-ion copper doping significantly improves the catalytic activity of alpha-MnO2 in CO oxidation, reducing the apparent activation energy to similar to 0.3 eV via strong electronic interactions between the frontier orbitals of copper ions and manganese ions.

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