Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 6, Pages 972-975Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09160b
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Funding
- National Key Research and Development Program of China [2018YFA0507900]
- NSFC [21602251]
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A copper-catalysed three-component iodoalkynylation reaction of arynes for the expeditious and versatile synthesis of o-alkynyl aryl iodides has been developed. Mechanism research shows that the reaction goes through two steps enabled by copper catalysis: the formation of 1-iodo-2-arylacetylene and the insertion of the aryne into a C(sp)-I bond.
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