Journal
JOURNAL OF CLEANER PRODUCTION
Volume 142, Issue -, Pages 1283-1295Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2016.09.008
Keywords
Hemp; Nanocellulose; Mechanical defibrillation; Mechanical isolation; High pressure homogenizer; Microfluidizer
Categories
Funding
- Ratchadapisek Sompoch Endowment Fund
- Chulalongkorn University [CU-58-034-AM]
- Ratchadapiseksomphot Endowment under Outstanding Research Performance Program [GF_58_08_23_01]
- 100th Anniversary Chulalongkorn University Fund
Ask authors/readers for more resources
Industrial hemp is a green economic plant for biogas and fuel. It is also used mainly in construction, paper, and textile industries. After harvested, the stubs of hemp are left as wastes. Therefore, the added value of this part is considered in this study. Mechanical defibrillation is an interesting method which does not require any harmful chemicals to be involved for size reduction. In this work, high-pressure homogenization by microfluidizer was carried out to defibrillate hemp fibers. Three investigating parameters, which were chemical pretreatment (delignification and hemicellulose removal), fiber concentration, and defibrillation time, were studied. It was found that chemical pretreatment enhanced capability of mechanical defibrillation in which nanofibrillated cellulose could be obtained shortly by microfluidizer (starting from only 15 min defibrillation to obtain 20-50 nm fiber diameters). Higher fiber concentration during defibrillation provided greater degree of polymerization and slightly higher thermal degradation temperature. Meanwhile, longer defibrillation time resulted in smaller and more uniformity of size of nanofibers and provided significant lower degree of polymerization and minor decrease in thermal degradation temperature. However, no significant change on crystallinity was observed. From the obtained results, 0.7% w/v of fiber concentration and 120 min defibrillation time using chemi-mechanical method provided the most uniformity of fiber size and the highest transparency of an aqueous suspension as well as its cast film. (C) 2016 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available