4.7 Article

An ecofriendly dyeing of wool with supercritical carbon dioxide fluid

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 143, Issue -, Pages 269-277

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2016.12.115

Keywords

Ecofriendly dyeing; Wool; Supercritical carbon dioxide; Disperse dye; Performance

Funding

  1. Program of High-end Foreign Experts Working in the Educational and Cultural Sector [GDW20162100068]
  2. Group Project of Liaoning Provincial Department of Education [2016J003]
  3. China Scholarship Council under the Grant CSC [201406790023]
  4. Science Fund from Dalian City [2014A11GX030]

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Dyeing feasibility of wool was investigated with Disperse Red 54, Disperse Blue 183, Disperse Red 153, Disperse Blue 148, Disperse Red 92, and Disperse Yellow 82 in supercritical carbon dioxide. The effects of dyeing temperature, pressure, time, dye mesh number, as well as CO2 flow on the K/S values and fixation rates of the wool samples were discussed. The results showed that the higher K/S values and fixation rates were obtained with Disperse Red 153 and Disperse Blue 148 in comparison with other disperse dyes. Simultaneously, the K/S values and the fixation rates were improved gradually from 70 degrees C to 110 degrees C, 15 MPa to 25 MPa, 60 min to 120 min, as well as 40 mesh number to 100 mesh number for Disperse Red 153, and from 80 degrees C to 120 degrees C, 15 MPa to 25 MPa, 60 min to 120 min, as well as 40 mesh number to 100 mesh number for Disperse Blue 148 during supercritical carbon dioxide dyeing procedure. Moreover, excellent permeability and color fastness were obtained whereas the breaking force and tensile strength of the dyed wool fibers were reduced slightly after supercritical carbon dioxide dyeing. (C) 2016 Elsevier Ltd. All rights reserved.

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