Journal
ACS APPLIED NANO MATERIALS
Volume 3, Issue 1, Pages 264-273Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsanm.9b01939
Keywords
electric double layer; TiO2 nanoparticles; water dissociation; liquid microjet; photoelectron spectroscopy; X-ray absorption spectroscopy
Funding
- Egyptian Ministry of Higher Education
- Ain Shams University
- Egyptian Culture Office in Berlin
- Deutsche Forschungsgemeinschaft (DFG) [1109]
- DFG [SE 2253/3-1]
- Max Planck Society
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We report an experimental observation of a significant amount of hydroxide (OH-) created upon water dissociation and subsequently trapped around TiO2 nanoparticles dispersed in NH4OH aqueous solution. The hydroxide species is identified and quantified by a combination of photoemission and photon emission X-ray spectroscopies conducted on liquid samples using a liquid microjet. Unlike previous X-ray studies that observed only a few monolayers of water coverage on TiO2 surfaces and found maximally submonolayer of OH-, the true aqueous environment adopted in this study enables ion mobility and the separation of the water dissociation products H+/OH-. This facilitates the formation of OH- diffused multilayer in which the trapped OH- ions are discovered to coordinate with three water molecules to form a tetrahedral hydration configuration. The negatively charged diffuse layers, together with the positive NH4+ Stern layers, constitute >0.8 nm thick electric double layers around the TiO2 nanoparticles. The large observed amount of hydroxide indicates a high efficiency of water dissociation for the TiO2 catalyst, a promising result for H generation in true aqueous environments.
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