Journal
JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 107, Issue -, Pages 1-7Publisher
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2016.12.009
Keywords
Geminal dicationic ionic liquid (GDIL); Surface tension; Surface thermodynamic function; Density; Critical temperature; Parachor
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Funding
- Research Council of University of Isfahan
- national elite foundation of Iran
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Surface tensions and densities of three imidazolium-based geminal dicationic ionic liquids (GDILs) with the bis(trifluoromethylsulfonyl)imide, [NTf2](-), as a common anion, have been measured at ambient pressure at different temperatures in the range from 296.00 to 353.15 K. The surface thermodynamic functions such as surface entropy and surface enthalpy were derived from the temperature dependence of surface tension which indicated the surface ordering in these GDILs. As well as the parachor, the critical temperatures of these systems have been estimated using the Guggenheim and Eotvos correlations. In each case, the results of GDILs have been compared with the results of corresponding traditional mono cationic ILs (MILs). Also, the relations between the surface tension and density and also surface tension and viscosity data have been demonstrated and discussed. (c) 2016 Elsevier Ltd.
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