Thermal properties and reliability of eutectic mixture of stearic acid-acetamide as phase change material for latent heat storage

The thermal properties and reliability of the stearic acid (SA) with acetamide (AC) binary mixture were characterized using differential scanning calorimetry (DSC), powder X-ray diffraction (XRD), thermogravimetric analysis (TG) and Fourier transform infrared spectroscopy (FT-IR). The phase diagrams for the SA-AC binary mixture with AC in the metastable and the stable form were constructed. The eutectic system with stable AC is 0.604 mol fraction SA, and displayed a melting temperature (T-m) of 64.55 degrees C and latent heat of melting (Delta H-m) of 193.87J.g(-)1. The eutectic systems with metastable AC are 0.397 and 0.604 mol fraction SA. The melting temperatures are 62.23 degrees C and 62.54 degrees C, and latent heats of fusion are 222.10 J.g(-1) and 194.28J.g(-1), respectively. Following accelerated thermal cycling tests, TG and FTIR analysis indicate that the eutectic mixture (chi(sA) = 0.397) with the metastable AC has good cyclic and thermal stability. The results show that the SA-AC eutectic mixture use as phase change material (PCM) possess good prospect for low temperature thermal energy storage (TES) applications. (C) 2016 Elsevier Ltd.