4.5 Article

Measurements of isothermal (vapour plus liquid) equilibrium for the 1,1,2,2-1,1,2,2-tetrafluoroethane (R134) + cis-1,3,3,3-tetrafluoropropene (R1234ze(Z)) system at temperatures from (303.150 to 343.150) K

Journal

JOURNAL OF CHEMICAL THERMODYNAMICS
Volume 111, Issue -, Pages 20-26

Publisher

ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jct.2017.03.010

Keywords

Refrigerants; 1,1,2,2-1,1,2,2-Tetrafluoroethane cis-1,3,3,3-Tetrafluoropropene; Vapour liquid equilibrium

Funding

  1. National Natural Sciences Foundation of China [51376188, 51625603]

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The isothermal (vapour + liquid) equilibrium data for the 1,1,2,2-1,1,2,2-tetrafluoroethane (R134) + cis-1,3,3,3-tetrafluoropropene (R1234ze(Z)) system were determined by the static-analytical method at five temperatures from (303.150 to 343.150) K. The standard uncertainties of the temperature, pressure and composition were less than 5 mK, 0.0005 MPa, and 0.005, respectively. The experimental results were correlated by the Peng-Robison (PR) equation of state (EoS) with the Huron-Vidal (HV) mixing rule involving the non-random two-liquid (NRTL) activity coefficient model. The correlated results show good agreement with the experimental data. The average absolute relative deviations of pressure are between 0.20% and 0.35%, while the average absolute deviations of vapour phase mole fraction lay between 0.006 and 0.007. Azeotropic behaviour can be observed at four temperatures from (303.150 to 333.150) K, while zeotropic behaviour can be found at 343.150 K. (C) 2017 Elsevier Ltd.

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