Journal
DALTON TRANSACTIONS
Volume 49, Issue 6, Pages 1731-1735Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d0dt00017e
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- Deutsche Forschungsgemeinschaft (DFG)
- DFG [HU 2512/1-1]
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The new bidentate bisphosphino ligand (5-Ph2P-Ace-6-SiMe2)(2) (1) binds rhodium(i) chloride and brings it into close proximity to a strong unpolar sigma-Si-Si bond, in which it immediately inserts. In the spirocyclic Rh(iii) product of the oxidative addition, (5-Ph2P-Ace-6-SiMe2)(2)RhCl (2), the two Si atoms are still close enough to engage in weak non-covalent interactions.
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