4.7 Article

Twisted Schiff-base macrocycle showing excited-state intramolecular proton-transfer (ESIPT): assembly and sensing properties

Journal

CHEMICAL COMMUNICATIONS
Volume 56, Issue 15, Pages 2304-2307

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09540c

Keywords

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Funding

  1. National Natural Science Foundation of China [21871063, 21961007]
  2. Guizhou Provincial Natural Science Foundation [20165656, 20175788, 20192792, 20185779-14, 20181033]

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A Schiff-base macrocyclic host (MH) showing ESIPT and AIEE is reported for the first time; the fluorescent macrocycle exhibited good pH tolerance and could serve as a probe for Cu2+ and Fe3+ ion sensing and removal. In addition, a series of size-tunable nanoparticles was fabricated by the self-assembly of free MH and its coordination complex with Fe3+ in THF/water solution.

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