4.6 Article

Visible-light-driven metal-free aerobic synthesis of highly diastereoselective phosphinoylpyrroloindoles

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 18, Issue 7, Pages 1354-1358

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02730k

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Funding

  1. Council of Scientific and Industrial Research (CSIR), New Delhi

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A visible-light-driven metal-free phosphorus radical mediated construction of 2-phosphinoyl-3H-pyrrolo[1,2,a]indoles is described. This mild tandem phosphinoylation/cyclization protocol utilizes air as a green oxidant and proceeds in a short span of time at room temperature with high functional group tolerance, and excellent chemo- and diastereoselectivity.

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