Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 18, Issue 7, Pages 1354-1358Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9ob02730k
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- Council of Scientific and Industrial Research (CSIR), New Delhi
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A visible-light-driven metal-free phosphorus radical mediated construction of 2-phosphinoyl-3H-pyrrolo[1,2,a]indoles is described. This mild tandem phosphinoylation/cyclization protocol utilizes air as a green oxidant and proceeds in a short span of time at room temperature with high functional group tolerance, and excellent chemo- and diastereoselectivity.
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