Journal
SN APPLIED SCIENCES
Volume 2, Issue 2, Pages -Publisher
SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s42452-020-1985-z
Keywords
Click chemistry; Redox polymerization; Comb-type graft copolymer; Poly(epichlorohydrin); Poly(methyl methacrylate)
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Funding
- Kafkas University Scientific Research Fund [2018-FM-77]
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The synthesis of poly(epichlorohydrin- g-methyl methacrylate) [poly(ECH-g-MMA)] comb-type graft copolymers were carried out by use of a click chemistry to graft terminally propargyl poly(methyl methacrylate) (PMMA-propargyl) to poly(epichlorohydrin) azido (PECH-N-3). For this purpose, PECH-N-3 was synthesized by using poly(epichlorohydrin) and sodium azide. PMMA-propargyl was obtained by reaction of methyl methacrylate and propargyl alcohol via redox polymerization technique. By using PECH-N-3 and PMMA-propargyl, the comb-type graft copolymers were obtained. Characterization of the modified homopolymers and the comb-type graft copolymers was performed by using FT-IR, H-1-NMR, SEM, GPC, and elemental analysis techniques. Thermal transitions and degradation features of the comb-type graft copolymers were investigated by using DSC and TGA methods. Spectroscopic and thermal analyses revealed that both group modifications and coupling reactions were successfully achieved.
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