Journal
DALTON TRANSACTIONS
Volume 44, Issue 38, Pages 16802-16809Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt02276b
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Funding
- DFG
- Helmholtz Research School Energy-related Catalysis
- FCI
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Functionalized 4,4'-biphenyldicarboxylic acid molecules with additional amine, alkyne, azide or nitro groups were prepared and applied in the synthesis of novel metal-organic frameworks and mixed-linker metal-organic frameworks isoreticular to DUT-5. The properties of the frameworks could be tuned by varying the number of functional groups in the materials and the amine groups were employed in post-synthetic modification reactions without changing the framework structure or significantly decreasing the porosity of the materials.
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