Journal
DALTON TRANSACTIONS
Volume 44, Issue 19, Pages 8833-8838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00269a
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Funding
- RFBR [14-03-31774]
- Office of Basic Energy Sciences of the U.S. Department of Energy [DE-FG02-07ER15885]
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Ni-catalyzed electroreductive olefin perfluoroalkylation affords both monomeric and dimeric products depending on the reaction media. Recycling of the catalyst can be achieved by immobilization of a (bpy)-NiBr2 complex on silica nanoparticles decorated with anchoring amino-groups. Switching the homogeneous and heterogeneous catalysts is found to be one more factor to control the product ratio. This catalytic technique is both green and atom economical and combines the advantages of nanoheterogeneous catalysis and electrocatalysis.
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