Journal
DALTON TRANSACTIONS
Volume 44, Issue 45, Pages 19674-19681Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03009a
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Funding
- Russian Science Foundation [14-23-00016]
- Office of Basic Energy Sciences of the U. S. Department of Energy [DE-FG02-13ER16369]
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A new iron-catalyzed reaction for the coupling of perfluoroalkyl iodides (RFI) with aromatic substrates is described. The perfluoroalkylated arene products are obtained in good to excellent yields in the presence of a [(bpy)Fe(II)] catalyst (10%) electrochemically regenerated or generated from [(bpy)Fe(III)] at room temperature. The development, scope, and preliminary mechanistic studies of these transformations are reported.
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