Journal
CHEMICAL COMMUNICATIONS
Volume 56, Issue 14, Pages 2159-2162Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cc09523c
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Funding
- National Natural Science Foundation of China [U1608222]
- State Key Laboratory of Fine Chemicals [KF1606]
- State Key Laboratory of Chemo/Biosensing and Chemometrics [2016005]
- Special Fund for Agro-scientific Research in the Public Interest of China [201503108]
- Hunan Provincial Innovation Foundation for Postgraduate [CX20190058]
- Fundamental Research Funds for the Central Universities of Central South University [2019zzts002]
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Introduction of a tetrahydroquinoxaline donor into boron difluoride complexes largely extended their emissions (617-684 nm), highly improved their fluorescence quantum yields (up to 0.68) and greatly increased their Stokes shifts (up to 209 nm). These new fluorescent dyes showed reversible ratiometric solid-state fluorescence changes upon switched acid/base fumings. Significantly, these boron difluoride complexes were successfully utilized as imaging agents in living cells and zebrafish.
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