Ethylene polymerisation and ethylene/norbornene copolymerisation by using aryloxo-modified vanadium(v) complexes containing 2,6-difluoro-, dichloro-phenylimido complexes

Aryloxo- modified vanadium(V) dichloride complexes containing a dichloro- or difluoro-phenylimido ligand of the type, V(N-2,6-X2C6H3)Cl-2(O-2,6-R2C6H3) [X = Cl (1), F (2); R = Me (a), F (b)], showed remarkable catalytic activity in ethylene polymerisation and the copolymerisation with norbornene (NBE) in the presence of Et2AlCl; the activities were higher than that of V(N-2,6-Me2C6H3)Cl-2(O-2,6-Me2C6H3) reported previously. Complex 1a is a suitable catalyst precursor in terms of not only the activity, but also synthesis of high molecular weight copolymers with both unimodal molecular weight distributions and uniform compositions.