4.7 Article

α-Diimine nickel complexes of ethylene and related alkenes

Journal

DALTON TRANSACTIONS
Volume 44, Issue 37, Pages 16228-16232

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt02333e

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Funding

  1. National Natural Science Foundation of China [21273170]

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A series of nickel mono(alkene) complexes, [LNi(alkene)], which consist of nickel(0) and neutral alpha-diimine ligand L (L = [(2,6-iPr(2)C(6)H(3)) NC(Me)](2)), have been synthesized. The bonding and structures of the complexes were studied by X-ray diffraction, spectroscopic methods, and DFT computations.

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