Journal
JOURNAL OF MATERIALS CHEMISTRY C
Volume 8, Issue 8, Pages 2669-2675Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c9tc06376e
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Funding
- Hong Kong Research Grants Council [PolyU153062/18P]
- Areas of Excellence Scheme of HKSAR [AoE/P-03/08]
- Hong Kong Polytechnic University [1-ZE1C]
- Ms Clarea Au for the Endowed Professorship in Energy [847S]
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Herein, we report novel supermolecular heterojunctions with six kinds of multi-layer core-shell microstructures, which consist of up to three CT complex components that realize programmable fabrication with defined luminescent CT domains and controllable multi-color-emitting properties. A stepwise seeded-growth route was designed using these CT cocrystals as seed and growing units during the process of fabrication where solution-epitaxy growth would occur based on their perfect lattice matching. This rational multi-step synthetic route furnishes a new insight into developing and constructing more sophisticated organic heterogeneous materials.
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