4.7 Article

Prussian blue analogues Mn[Fe(CN)(6)](0.6667)center dot nH(2)O cubes as an anode material for lithium-ion batteries

Journal

DALTON TRANSACTIONS
Volume 44, Issue 38, Pages 16746-16751

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt03030g

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Funding

  1. National Natural Science Foundation of China [NSFC 21173049]
  2. Research Fund for the Doctoral Program of Higher Education of China [RFDP 20133514110002]

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In the present work, Prussian blue analogues, Mn[Fe(CN)(6)](0.6667)center dot nH(2)O (Mn-PBA), were synthesized by a simple synthetic route and characterized by XRD, SEM, TEM, FTIR and TGA. When this material was firstly used as an anode for lithium-ion batteries, it exhibited a large capacity, good rate capability and cycling stability with a high Coulombic efficiency. For instance, a reversible capacity of 295.7 mA h g(-1) can be achieved after 100 cycles at 200 mA g(-1).

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