4.6 Article

CuII/H-USY as a regenerable bifunctional catalyst for the additive-free C-H amination of azoles

Journal

CATALYSIS SCIENCE & TECHNOLOGY
Volume 10, Issue 4, Pages 940-943

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c9cy02153a

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Funding

  1. NMBP-01-2016 Program of the European Union's Horizon 2020 Framework Program [720996]
  2. FWO [G0D0518N]

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A copper-exchanged H-USY zeolite catalyst was developed for the direct C-H amination of azoles with secondary amines in HFIP. The reaction was performed under air without any external additive. The Cu/H-USY catalyst could be regenerated for further re-use without significant decrease in activity.

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