4.7 Article

Enhancement of the initial hydrogenation of Mg by ball milling with alkali metal amides MNH2 (M = Li or Na)

Journal

DALTON TRANSACTIONS
Volume 44, Issue 38, Pages 16694-16697

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01847a

Keywords

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Funding

  1. National Natural Science Foundation of China [51461010, 51401059, 51371060, 51361006]
  2. Guangxi Natural Science Foundation [2013GXNSFBA019034, 2013GXNSFBA019239, 2014GXNSFAA118043, 2014GXNSFAA118333]
  3. Guangxi University Research Project [YB2014132]
  4. Guangxi Collaborative Innovation Center of Structure and Property for New Energy Materials

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The introduction of 4 wt% of MNH2 (M = Li, Na) and other additives (Li, MgH2, NaCl, and NaBr) into pure Mg by ball milling greatly enhances the first hydrogenation (activation). Under 2 MPa of H-2 at 608 K, the best activation performance is achieved with the NaNH2 additive.

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