Journal
DALTON TRANSACTIONS
Volume 44, Issue 27, Pages 12074-12077Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt00108k
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Funding
- U. S. National Science Foundation [CHE-1265608]
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Two cobalt compounds, Cp*Co(CO)I-2 (1) and CpCo(CO)I-2 (2) (Cp* = eta(5)-C5Me5, Cp = eta(5)-C5H5), catalyze the dehydrogenation of ammonia borane under either anaerobic or aerobic conditions and are also effective hydrogenation catalysts for alkenes and alkynes using ammonia borane as a hydrogen source, also in the presence of air.
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