4.7 Article

Cryptic noninnocence: FeNO corroles in a new light

Journal

DALTON TRANSACTIONS
Volume 44, Issue 22, Pages 10146-10151

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5dt01495f

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Funding

  1. Research Council of Norway through FRINATEK grant [163054, 231086]
  2. Centre of Excellent grant [179568/V30]
  3. NOTUR grant [NN4654K]

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Multiple lines of evidence, including electronic absorption spectroscopy, infrared spectroscopy, and broken-symmetry DFT calculations, indicate that the well-known FeNO corroles, long assumed to be {FeNO}(6) complexes, are in fact better described as {FeNO}(7)-(corrole(center dot 2-)).

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